Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformations.
نویسندگان
چکیده
Novel ruthenium(II) complexes were obtained as a result of a stoichiometric reaction of Grubbs' benzylidene second generation catalysts with 3-nitropropene. These stable complexes, formally ruthenaisoxazole N-oxide derivatives, display activity in both metathesis and non-metathetic processes such as cycloisomerisation, isomerisation and transfer hydrogenation.
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عنوان ژورنال:
- Chemical communications
دوره 49 7 شماره
صفحات -
تاریخ انتشار 2013